[2] Benfica 3-0 Barcellona [4] 2021-09-29 19:00
stadio: Estadio do Sport Lisboa e Benfica Round: 2
Arbitro: Daniele Orsato Home Manager: Jorge Jesus Away Manager: Ronald Koeman
Home History
| Portogallo - Primeira Liga | 2021/09/25 17:00 | Guimaraes v Benfica | W | 1-3 |
| Portogallo - Primeira Liga | 2021/09/20 18:00 | Benfica v Boavista | W | 3-1 |
| UEFA Champions League | 2021/09/14 19:00 | Dinamo Kiev v Benfica | D | 0-0 |
| Portogallo - Primeira Liga | 2021/09/11 17:00 | Santa Clara v Benfica | W | 0-5 |
| Portogallo - Primeira Liga | 2021/08/29 17:00 | Benfica v CD Tondela | W | 2-1 |
| UEFA Champions League - Qual. | 2021/08/24 19:00 | PSV Eindhoven v Benfica | D | 0-0 |
| Portogallo - Primeira Liga | 2021/08/21 17:00 | Gil Vicente v Benfica | W | 0-2 |
| UEFA Champions League - Qual. | 2021/08/18 19:00 | Benfica v PSV Eindhoven | W | 2-1 |
Away History
| Spagna - Primera Division | 2021/09/26 14:15 | Barcellona v Levante | W | 3-0 |
| Spagna - Primera Division | 2021/09/23 20:00 | Cadiz v Barcellona | D | 0-0 |
| Spagna - Primera Division | 2021/09/20 19:00 | Barcellona v Granada | D | 1-1 |
| UEFA Champions League | 2021/09/14 19:00 | Barcellona v Bayern Monaco | L | 0-3 |
| Spagna - Primera Division | 2021/08/29 15:00 | Barcellona v Getafe | W | 2-1 |
| Spagna - Primera Division | 2021/08/21 20:00 | Atletico Bilbao v Barcellona | D | 1-1 |
| Spagna - Primera Division | 2021/08/15 18:00 | Barcellona v Real Sociedad | W | 4-2 |
| Amichevoli Europa | 2021/08/08 19:30 | Barcellona v Juventus | W | 3-0 |